Unexpected formation of stannolanes and trigonal bipyramidal tin complexes by radical cyclization reaction.
نویسندگان
چکیده
Optically active stannolanes and trigonal bipyramidal pentacoordinated tin complexes were readily prepared by radical cyclization of N-propargylated chiral aza-Morita-Baylis-Hillman adducts induced by Bu(3)SnH. A translocated radical through the cyclization attacked the Bu(3)Sn group in an S(H)2 manner.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 52 شماره
صفحات -
تاریخ انتشار 2012